光学诱导液晶薄膜制备及其在感测元件上的应用研究(I)

项目来源

台(略)府(略)金(略)B(略)

项目主持人

刘(略)

项目受资助机构

台(略)功(略)学(略)系(略)

项目编号

M(略)1(略)2(略)-(略)6(略)7

立项年度

2(略)

立项时间

未(略)

研究期限

未(略) (略)

项目级别

省(略)

受资助金额

1(略).(略)元(略)

学科

光(略)

学科代码

未(略)

基金类别

应(略)/(略)助

关键词

光(略)化(略);(略)L(略)膜(略)液(略)器(略)布(略)射(略)紫(略) (略)h(略)l(略)m(略)n(略);(略)L(略)i(略)d(略)y(略)l(略)l(略);(略)q(略) (略)s(略) (略)s(略) (略)i(略) (略)r(略)’(略)e(略)c(略)n(略)U(略)i(略)p(略)r(略)t(略)

参与者

未(略)

参与机构

未(略)

项目标书摘要:光学(略)性,可以呈现出立体(略)有机材料表现出异方(略)构上的不对称螺旋结(略)性及立体特异性等。(略)列光学活性有机化合(略)晶掺混,用以诱导出(略)液晶相。除了制备液(略)外,更将以本研究室(略)备出高分子分散液晶(略)构的异方性高分子膜(略)制的光子晶体膜,若(略),其将因折射率之不(略)及改变UV-vis(略)出气体或液体的感测(略)可视化的技术。本计(略),逐步完成最终的感(略)晶薄膜制备及其在感(略)nvestigat(略)structure(略)s in poly(略)zed liqui(略)induced b(略)adiation (略)ion for s(略)es 第一年计划光(略)单体的合成 Syn(略)hiral Com(略)Multifunc(略)mers 本年度将(略)中心的化合物或单体(略)活性,同时亦具有多(略)、胺基、氢氧基等。(略)测系统中的液晶化合(略)子後,与充填於系统(略)生相互作用力,以达(略)详细的光学活性化合(略)步骤项中详细叙述。(略),将使用FTIR及(略)构。光学活性值,将(略)谱及萤光光谱特性,(略)未来将使用UV-v(略)计,光波长为介於2(略)UV波段),及40(略)见光波段)间,因此(略)如光学活性化合物与(略)可被期待具有明显的(略)晶螺旋距的调配及光(略)justing o(略)ystal Pit(略)brication(略)c Films 本(略)合成的光学活性化合(略)具有螺旋距的胆固醇(略)学活性化合物在液晶(略)的大小。以掺混浓度(略)将会有一系列详细探(略)体,以光聚合法制备(略)膜。所制备的液晶薄(略)制薄膜在UV-vi(略)细探讨。未来将以环(略)对液晶薄膜的物理变(略)UV-vis光谱的(略)第三年计划液晶感测(略) Fabricat(略)racteriza(略)uid Cryst(略)ing devis(略)年所得结果,进行液(略)力,例如温度、压力(略)而改变液晶膜反射光(略),造成在UV-vi(略)原理可以计测微量温(略)质侦测。又,前一年(略)子结构薄膜,会因为(略)物的折射率不同,而(略),直接显现於UV-(略)该些外力及化合物种(略)计成检测元件。本年(略)制备高分子薄膜进行(略)可以完成高感度液晶(略)测。

Applicati(略): Chiral (略)sually re(略)pecificit(略)tereo spe(略)ination p(略)n the pre(略)iral fiel(略)mpounds r(略)ficant as(略)ysical pr(略)r example(略)of asymme(略)l structu(略)stereo-se(略)nd stereo(略)y.In this(略)re going (略)ze a seri(略)al compou(略)g of the (略) compound(略)ercially (略)iquid cry(略) to the f(略) choleste(略)ral smect(略)rystals.F(略)of polyme(略) liquid c(略)s(PDLC)an(略)liquid cr(略)ilms impr(略)cholester(略)rystals u(略)thod deve(略)r lab via(略)tion will(略) out.Comp(略)as filled(略)rinted fi(略)nge the r(略)ndex of t(略)ads to th(略) of refle(略)as well a(略)ectra.Liq(略)line sens(略) will be (略)ing such (略)nd skills(略)rch progr(略) of follo(略)yearly su(略)导液晶薄膜制备及其(略) Investig(略)e structu(略)ons in po(略)lized liq(略)s induced(略)rradiatio(略)ption for(略)ices 1st (略)m Synthes(略)l Compoun(略)ifunction(略) In the 1(略)erious of(略)d chiral (略)ill be sy(略)ome of fu(略)oups will(略)ced onto (略)l compoun(略)ple,carbo(略)nd hydrox(略)he introd(略)onal grou(略)ract with(略)stals and(略)sized pol(略)es.Such i(略)may cause(略)cal prope(略)e,for exa(略)tive inde(略)d UV-vis (略)variation(略)he achiev(略)terials a(略)ing chang(略)eatiled s(略)ocess and(略)structure(略)scribed i(略)of Study (略) synthesi(略)compounds(略)rs will b(略)d using F(略)NMR.Optic(略)es will b(略) using au(略)arimetry.(略)tra of th(略)ed compou(略)so be mea(略)ength of (略)tra is be(略) to 400nm(略)and 400nm(略)isible ra(略)ingly,a s(略)ion of su(略)hange is (略) be detec(略)size sens(略) of the p(略)liquid cr(略)ensing de(略)ear Progr(略)g of Liqu(略)Pitches a(略)ion of Ph(略)s Chiral (略)ynthesize(略)rst year (略)d to blen(略)ercially (略)mectic an(略)iquid cry(略)he fabric(略)olesteric(略)stals wit(略) pitches.(略)on of chi(略)ds in liq(略) mixture (略)the pitch(略)crystals (略)ed.Study (略)ct of chi(略)ds on liq(略) pitch va(略)ll be car(略)ltifuncti(略)rs will b(略)o the mix(略)e imprint(略)onic crys(略)ctions vi(略)rization.(略)trometry (略)ared PDLC(略)the impri(略)ic films (略)estigated(略)surroundi(略)s and con(略)ges on th(略)d PDLC fi(略)tonic cry(略)is expect(略)nsed by t(略)n on the (略)tra.The f(略)d the pro(略)the prede(略)id crysta(略)ilms will(略)r the fab(略) sensing (略) Year Pro(略)ation and(略)zation of(略)stalline (略)ises Resu(略)d in the (略)ears will(略)he fabric(略)quid crys(略)sing devi(略)ons of th(略) and cond(略)urroundin(略)act with (略)ted liqui(略)ne films (略)anges of (略)color due(略) reflecti(略)l amount (略)ge may be(略)howing in(略)ctra.By u(略)kill,the (略)sensing d(略)be used f(略)ction of (略) and pres(略)s and pre(略)xic mater(略)tically,d(略) the mate(略)e the mat(略)DLC films(略)printed p(略)stalline (略)different(略) to Bragg(略)on.The va(略)uld be se(略)s spectra(略)kind of v(略)n of sens(略)ns.In thi(略) high sen(略)quid crys(略)ices are (略) be fabri(略) the desc(略)s.

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