HFO/HC、HFO/HFC/HC混合工质气液相平衡及PVTx性质研究

项目来源

国家自然科学基金(NSFC)

项目主持人

胡芃

项目受资助机构

中国科学技术大学

项目编号

51576187

立项年度

2015

立项时间

未公开

项目级别

国家级

研究期限

未知 / 未知

受资助金额

64.00万元

学科

工程与材料科学-工程热物理与能源利用-热物性与热物理测试技术

学科代码

E-E06-E0606

基金类别

面上项目

关键词

热力学性质 ; 共沸混合工质 ; 气液相平衡 ; 氢氟烯烃类 ; 混合制冷工质 ; Thermodynamic properties ; Refrigerant mixtures ; Vapor-Liquid Equilibria ; Azeotropic mixture ; HFOs

参与者

陈龙祥;赵盼盼;胡仁东;章高伟;潘健昌;蔡旭东;于晶晶

参与机构

中国科学院福建物质结构研究所;合肥通用机械研究院有限公司

项目标书摘要:在全球气候变暖的背景下,以氢氟烯烃类(HFOs)为主要组分的低GWP制冷混合工质成为目前替代工质研究的重要方向。但是其相关基础热力学数据还极为缺乏,因此本申请以HFO-1234yf、HFO-1234ze(E)、HFO-1234ze(Z)与HCs、HFCs组成的HFO/HC二元混合工质,HFO/HFC/HC三元混合工质为研究体系,开展气液相平衡性质、气相PVTx性质以及共沸特性的实验和理论研究。预期获得一批重要的基础实验数据,建立混合工质的气相维里方程,针对PR+vdW关联模型建立能够推算HFOs、HFCs、HCs混合工质体系气液相平衡性质的推算模型,并以此为基础结合实验测量研究HFO/HFC/HC三元混合工质共沸和近共沸性质。研究结果可以为寻求低GWP且性能优异的HFO/HC、HFO/HFC/HC混合工质提供基本数据和理论支持。

Application Abstract: In the background of global warming,refrigerant mixtures containing Hydrofluoroolefins(HFOs)are considered as promising candidates because of low GWP values.However,their primary thermodynamic properties are still very limited.In this proposal,HFO/HC binary mixtures and HFO/HFC/HC ternary mixtures containing HFO-1234yf,HFO-1234ze(E)and HFO-1234ze(Z)are selected for experimental and theoretical study on their vapor-liquid equilibria,gaseous PVTx and azeotropic properties.A number of experimental data of these important properties will be obtained.Gaseous Virial equations of state will be built.An estimation method for the VLE of mixtures containing HFOs,HFCs,HCs will be developed for the PR+vdW model.The azeotropic and near-azeotropic properties of HFO/HFC/HC ternary mixtures will be investigated.The results of the study can provided basic data and theoretical support for the research of the HFO/HC and HFO/HFC/HC mixtures with both of low GWP and excellent performances.

项目受资助省

安徽省

项目结题报告

HFO/HC、HFO/HFC/HC混合工质气液相平衡及PVTx性质研究结题报告(全文)

  • 排序方式:
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  • 1.异丁烷绝热毛细管流动均相流和分离流模型对比

    • 关键词:
    • 毛细管;绝热流动;摩擦系数;两相黏度;均相流模型;分离流模型;亚稳态流动
    • 束永辉;胡芃;Adnan Ibrahim;支亮辉;陈奇
    • 《中国科学技术大学学报》
    • 2022年
    • 7期
    • 期刊

    毛细管作为一种膨胀装置在小型制冷系统和热泵系统中得到了广泛的应用。尽管毛细管具有简单的几何形状,其中的绝热流动却是极其复杂的。本文对模拟异丁烷(R600a)在毛细管中绝热流动的均相流动模型和分离流模型进行了对比研究。研究了不

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  • 2.Analysis of Heat Transfer Oscillation and Buoyancy Effects of Supercritical R1234ze(E) Cooled in Horizontal Helically Coiled Tubes

    • 关键词:
    • Heat transfer coefficients;Oscillating flow;Buoyancy;Heat flux;Shear stress;Heat transfer performance;Mass transfer;Supercritical fluids;Effluent treatment;Gravitation ;Oceanography;Supercritical fluid extraction;Energy efficiency;Tubes (components);Turbulence models;Heat exchangers;Average absolute deviation;Centrifugal buoyancy;Centrifugal Forces;Environmental property;Helically coiled tubes;Lower temperatures;Oscillation mechanism;Shear-stress transport
    • Jiang, Yi-Ran;Hu, Peng
    • 《Journal of Thermal Science and Engineering Applications》
    • 2021年
    • 13卷
    • 6期
    • 期刊

    The helically coiled tubes (HCTs) have been attracting huge attention for enhancing the heat transfer of supercritical fluids and improving energy efficiency. Moreover, the new refrigerant R1234ze(E) has excellent environmental properties and system performance, but few researches have been concentrated on the supercritical R1234ze(E) heat transfer. In this work, the shear stress transport (SST) turbulence model is adopted for the numerical simulation of the cooling heat transfer performance of s-R1234ze(E) in horizontal HCT. The influences of heat flux, mass flux, coil pitch, and tube radius on the heat transfer coefficient, gravitational buoyancy effect, and centrifugal buoyancy effect are, respectively, investigated. Furthermore, the results reveal heat transfer oscillation occurs when Rig ? |cos ?|max >0.17, and the oscillation mechanism is analyzed. Different from that in the vertical HCT, the angle between the radial component of gravitational buoyancy and centrifugal force varies continuously in the horizontal helical tube, resulting in the fluid with lower temperature may locate in the inner-left region or the inner-right region. Subsequently, the heat transfer piecewise correlation for supercritical R1234ze(E) in horizontal HCT is developed. The average absolute deviation of the predicted results is 5.88%.
    © 2021 American Society of Mechanical Engineers (ASME). All rights reserved.

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  • 3.Measurements of Critical Properties of the Binary Mixture of 1,1,1-Trifluoroethane (HFC-143a) + trans-1,3,3,3-Tetrafluoropropene (HFO-1234ze(E))

    • 关键词:
    • VAPOR-LIQUID-EQUILIBRIA; CRITICAL PARAMETERS; PRESSURE MEASUREMENTS;SATURATED DENSITIES; TEMPERATURES; HFO-1234ZE(E); VISCOSITY
    • Zhang, Nan;Hu, Peng;Chen, Long-xiang;Liu, Ming-hou;Chen, Qi
    • 《JOURNAL OF CHEMICAL AND ENGINEERING DATA》
    • 2021年
    • 66卷
    • 7期
    • 期刊

    The critical temperatures and pressures of the binary mixture of 1,1,1-trifluoroethane (HFC-143a) + trans-1,3,3,3-tetrafluoropropene (HFO-1234ze(E)) were measured by a set of apparatus containing an optical cell that has a variable inner volume. The experimental measurements were carried out based on a static method, and the critical properties were determined by means of the observation of disappearance and reappearance of the meniscus. The experimental uncertainties in pressure, temperature, and mole fraction were estimated to be less than 6.2 kPa, 0.02 K, and 0.003, respectively. The experimental critical properties measured in this work were correlated by the Redlich-Kister method, and the correlated results showed a good agreement with experimental data.

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  • 4.Thermodynamic analysis for supercritical carbon dioxide brayton cycle by considering both thermal efficiency and cooler area

    • 关键词:
    • Carbon dioxide;Thermodynamic properties;Heat transfer coefficients;Thermal efficiency;Thermoanalysis;Supercritical fluid extraction;Cooling systems;Average heat transfers;Evaluation criteria;Logarithmic-mean temperature differences;Operating condition;Performance optimizations;Supercritical carbon dioxides;Thermal efficiency;Thermo dynamic analysis
    • Hu, Peng;Jiang, Yi-Ran;Zhang, Gao-Wei;Miao, Zhen
    • 《Journal of Thermal Science and Engineering Applications》
    • 2021年
    • 13卷
    • 1期
    • 期刊

    The performances of the supercritical carbon dioxide (sCO2) Brayton cycle with the recuperator were investigated by the simulation method. Evaluation criteria were proposed for system performance optimization. The calculation and analysis of the system thermal efficiency and the length of the cooler were performed. The effects of the inlet and outlet pressure of the expander, the heat transfer coefficient and the logarithmic mean temperature difference (LMTD) on the system thermal efficiency and the length of the cooler were investigated. The system thermal efficiency has a peak value with the increase of the expander inlet pressure. The peak value varies from 45% to 45.4% with different expander outlet pressures. The average heat transfer coefficient and the length of the cooler decrease with the increase of the inlet pressure, but the LMTD is on the contrary. When the expander inlet pressure is in the low-pressure stage (22–26 MPa), the thermal efficiency of the lower outlet pressure (8 MPa) is higher, which ranges from 44.3% to 45.4%. However, the length of the cooler is also larger (6.7–10.9 m). As the expander inlet pressure rises to the high-pressure stage (26–30 MPa), the higher outlet pressure (9.5 MPa) has a greater advantage in the thermal efficiency, and the range of efficiency is 44.7–45%. Similarly, the length of the cooler is the largest (4.5–8 m). Therefore, both the thermal efficiency and the length of the cooler should be fully considered in the design of the system operating conditions.
    Copyright © 2020 by ASME

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  • 5.Experimental and numerical investigation on heat transfer characteristics of supercritical R1234ze(E) cooled in horizontal tubes

    • 关键词:
    • Supercritical fluids;Energy conversion;Heat transfer coefficients;Tubes (components);Effluent treatment;Heat exchangers;Numerical methods;Average absolute deviation;Energy conversion systems;Experimental correlation;Experimental investigations;Heat transfer characteristics;Heat transfer correlation;Numerical investigations;Pseudo-critical temperature
    • Jiang, Yi-Ran;Hu, Peng;Ibrahim, Adnan
    • 《International Journal of Heat and Fluid Flow》
    • 2020年
    • 85卷
    • 期刊

    The heat transfer characteristics of supercritical fluids in tubes have been considered indispensable for the design and optimization of the heat exchanger and the energy conversion system. Specifically the cooling heat transfer of supercritical R1234ze(E) in horizontal tubes is a promising heat-power conversion technology; however, there is a scarcity of conducted research in available literature. The present work, the first-ever study in this direction, aims to thoroughly investigate the heat transfer characteristics of supercritical R1234ze(E) which is cooled in horizontal tubes. Experimental work was performed to thoroughly explore and inspect the heat transfer characteristics of supercritical R1234ze(E) passing through the tube of 4.12 mm diameter at 4–5 MPa pressure and 240–400 kg/m2 s mass flux. Furthermore, the simulation study, supporting the experimental investigation under the same conditions of pressure and mass flux, extended the range of tube diameter up to 9.44 mm. The effects of pressure, mass flux and tube diameter on the heat transfer coefficient were carefully analyzed in the present research work. Based on the simulation results and experimental results, heat transfer correlations were newly developed by separating the region above and below the pseudo-critical temperature. The average absolute deviation between the calculated Nusselt numbers by the numerical correlation and the simulation results was found 2.87%; the average absolute deviation between the calculated Nusselt numbers by the experimental correlation and the experimental results was found 5.3%.
    © 2020 Elsevier Inc.

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  • 6.Numerical study on thermal behavior and a liquid cooling strategy for lithium-ion battery

    • 关键词:
    • battery thermal management system; electrochemical-thermal model; heatgeneration; liquid cooling strategy; lithium-ion battery safety;PHASE-CHANGE MATERIALS; MANAGEMENT-SYSTEM; HEAT-GENERATION; PACK;PERFORMANCE; OPTIMIZATION; DISCHARGE; DESIGN; MODEL; FIRE
    • Xu, Wenjun;Hu, Peng
    • 《INTERNATIONAL JOURNAL OF ENERGY RESEARCH》
    • 2020年
    • 44卷
    • 9期
    • 期刊

    Investigation on the thermal behavior of the lithium-ion battery which includes the temperature response, heat contribution and generation, is of vital importance for their performance and safety. In this study, an electrochemical-thermal cycling model is presented for a 4 Ah 21700 type cylindrical single cell and 3x3 battery pack and the model is validated by experiment on a single cell. Thermal behavior on a single cell is first analyzed, the results show that the heat generated in the charge is smaller than the discharge, and the polarization heat contributes the most to total heat, especially under higher rate. It can also be concluded from the battery pack that the temperature of the cell inside the battery pack is significantly greater than the external battery, while the temperature difference exists the opposite regular due to the worst heat dissipation of the central cell. Finally, after taking the enhanced liquid cooling strategy, the maximum temperature is 320.6 K that is reduced by 9.38%, and the maximum temperature difference is 4.9 K which is reduced by 69.6% at 2C, meeting the requirements of battery thermal management system.

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  • 7.Performance analysis and optimization of engine waste heat recovery with an improved transcritical-subcritical parallel organic Rankine cycle based on zeotropic mixtures

    • 关键词:
    • Engine waste heat recovery; Transcritical-subcritical; Parallel organicRankine cycle; Zeotropic mixture; Design parameters; Performanceanalysis;PARAMETRIC ANALYSIS; ORC SYSTEM; THERMODYNAMIC ANALYSIS; DESALINATIONSYSTEM; ENERGY RECOVERY; SIMULATION; REFRIGERATION; TEMPERATURE;EXPANSION; DORC
    • Zhi, Liang-Hui;Hu, Peng;Chen, Long-Xiang;Zhao, Gang
    • 《APPLIED THERMAL ENGINEERING》
    • 2020年
    • 181卷
    • 期刊

    Effective recovery of engine waste heat is a key strategy to alleviate energy and environmental issues. In this study, an improved transcritical-subcritical parallel organic Rankine cycle based on zeotropic mixtures is proposed to recover engine waste heat. Firstly, the proposed system is compared with other systems and shows the best performance. Then energy and exergy analyses are conducted, and three design parameters are analyzed. According to the results, for each turbine inlet temperature of high-pressure branch, the system performance initially increases then decreases with turbine inlet pressure of high-pressure branch, and the net power output firstly increases then decreases with evaporation temperature of low-pressure branch. Furthermore, the effect of composition of zeotropic mixtures on system performance is investigated, and zeotropic mixtures R600a/R601a and R600/R601 are compared. The results indicate that adopting zeotropic mixture can improve system performance significantly, and system based on R600/R601 performs better than based on R600a/R601a. Finally, performance optimization of system is conducted. The results show that system based on R600/R601 (0.5/0.5) achieves the maximum net power output of 114.47 kW which is higher 10.68% and 6.42% than based on pure R600 and R601 respectively, and the engine power output is improved by 11.49%.

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  • 8.超临界R134a水平圆管内冷却换热模拟研究

    • 关键词:
    • 超临界;R134A;水平圆管;数值模拟;冷却换热
    • 苗震;胡芃;章高伟
    • 《工程热物理学报》
    • 2020年
    • 1期
    • 期刊

    采用增强壁面函数的标准k-ε模型对超临界R134a水平圆管内冷却换热进行了模拟研究.分析了管内不同截面上流体温度、速度和湍动能的分布情况及对应关系。研究了质量流量和浮升力对换热系数的影响。结果表明,流体速度随着温度的降低而减小

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  • 9.Thermodynamic analysis of an innovative transcritical CO2 parallel Rankine cycle driven by engine waste heat and liquefied natural gas cold

    • 关键词:
    • Engine waste heat; Liquefied natural gas cold; Transcritical CO2parallel Rankine cycle; Thermodynamic analysis; Parametric analysis;DIOXIDE POWER CYCLE; PERFORMANCE ANALYSIS; PARAMETRIC ANALYSIS;ZEOTROPIC MIXTURES; GEOTHERMAL-ENERGY; DESIGN ANALYSIS; EXERGY ANALYSIS;OPTIMIZATION; RECOVERY; SYSTEM
    • Zhi, Liang-Hui;Hu, Peng;Chen, Long-Xiang;Zhao, Gang
    • 《ENERGY CONVERSION AND MANAGEMENT》
    • 2020年
    • 209卷
    • 期刊

    In this study, to promote the performance of engine waste heat recovery, for the first time, an innovative transcritical CO2 parallel Rankine cycle driven by engine waste heat and liquefied natural gas cold is proposed and studied. Firstly, the thermodynamic analysis including energy and exergy analysis is conducted, and heat transfer requirement analysis for fluids in different working state is presented. Then parametric analysis is conducted, the effects of different parameters on system performance are investigated. According to the results, by adjusting the temperature and pressure of cycle, system performance can be maximized, and with the utilization of liquefied natural gas cold, the entire system achieves the increase of power output of 20%, improvement of thermal and exergy efficiency of 2%. When condensation temperature changes from 20 degrees C to -10 degrees C, system power output has an improvement of 86% (from 103.37 kW to 192.37 kW) while heat transfer area only increases by 25% (from 162.83 m(2) to 218.72 m(2)). Moreover, a performance comparison of system based on CO2 and six widely-used organic fluids is carried out, and results demonstrate that CO2 has better performance than organic fluids. Furtherly, the optimization analysis of system power output is conducted. The results indicate that the proposed system achieves the maximum power output of 205.60 kW, at the same time, the engine power output can be improved by 21.42%. Finally, an exergy destruction analysis is presented, and the results show that the exergy destruction rate of condenser reaches to 70.94% of total exergy destruction due to the large temperature difference between CO2 and liquefied natural gas.

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  • 10.Retrofitting low-cost heating ventilation and air-conditioning systems for energy management in buildings

    • 关键词:
    • Energy crisis; Retrofitting; Occupancy detection; Energy efficientbuildings; Air-conditioning;RESEARCH-AND-DEVELOPMENT; OCCUPANCY; SPACE
    • Rashid, Syed Aftab;Haider, Zeeshan;Hossain, S. M. Chapal;Memon, Kashan;Panhwar, Fazil;Mbogba, Momoh Karmah;Hu, Peng;Zhao, Gang
    • 《APPLIED ENERGY》
    • 2019年
    • 236卷
    • 期刊

    Developing countries such as Pakistan are experiencing severe energy crises because of an increasing difference between energy demand and energy production. Since buildings are the major consumers of energy in Pakistan, immediate steps must be taken to reduce energy consumption by devising energy efficient measures for buildings. The majority of buildings in the country use distributed heating/cooling devices, i.e:, air conditioners (A/Cs), to regulate building temperature. These A/Cs consume most of the energy in the buildings and are often subjected to problems such as heating or cooling unoccupied spaces and overheating/overcooling some areas in the building. These problems arise mainly because of independent manual controls of A/Cs and can be addressed by installing centralized heating, ventilation, and air-conditioning (HVAC) systems. However, the cost of deploying an actual HVAC system in these buildings remains high. Costs are associated with disruption to occupants as well as the dollar cost of installing the HVAC infrastructure. Moreover, the cost associated with removal or replacement of the existing A/C units is also substantial. Therefore, in this work, we abstract the functionality of the HVAC system by using the existing distributed heating/cooling infrastructure in buildings to provide a low-cost centralized command and control mechanism namely Retrofitting low-cost Heating Ventilation and Air Conditioning (RetroHVAC) system. We designed an occupancy detection system and incorporated it into the RetroHVAC system to enhance its energy-saving potential. Additionally, a desktop application was designed to enable user interaction and policy enforcement. Experimental evaluation comparing different RetroHVAC control strategies based on time scheduling, temperature threshold monitoring, and real-time occupancy information show that the RetroHVAC system can substantially reduce the building energy consumption without compromising user comfort.

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