压缩空气溶液干燥新方法及其关键基础问题研究
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1.Development of vapor pressure model for mixed liquid desiccants near saturated solubility
- 关键词:
- Hydrostatic pressure;Osmosis;Ions;Vapor pressure;Liquids;Dipole moment;Solubility;Charge interactions;Charge-dipole interaction;Osmotic coefficient;Prediction accuracy;Saturated solubility;Solute concentrations;Statistical thermodynamic modeling;Vapor pressure model
- Che, Chunwen;Yin, Yonggao
- 《25th IIR International Congress of Refrigeration, ICR 2019》
- 2019年
- August 24, 2019 - August 30, 2019
- Montreal, QC, Canada
- 会议
A statistical thermodynamic model is proposed to predict the vapor pressure of mixed liquid desiccant solutions near saturated solubility by re-quantifying the weight of interactions between all species in solution. The model considers that charge interaction between ions and non-charge interaction between all species are still dominant, and charge-dipole interaction between ions and solvent molecules increases with the increase of solute concentration. Rigorous expressions are given to calculate the interactions: ion-ion charge interaction is described by modifying the Fowler-Guggenheim theory, charge-dipole interaction is expressed by combining the McMillan-Mayer osmotic coefficient theory with the Debye-Hückel theory, and non-charge interaction is calculated based on the extended UNIQUAC equation. The prediction accuracy comparison with two typical models shows that the new model has better accuracy for mixed liquid desiccants near saturated solubility.
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© 2019 International Institute of Refrigeration. All rights reserved.2.Investigation on drying performance and alternative analysis of different liquid desiccants in compressed air drying system
- 关键词:
- Compressed air; Liquid desiccant; Drying performance; Energy consumption;LOCAL COMPOSITION MODEL; EXCESS GIBBS ENERGY; DEHUMIDIFICATION;REGENERATION; SOLVENT; HEAT; LITHIUM
- Zhan, Changfeng;Yin, Yonggao;Guo, Xiaoshuang;Jin, Xing;Zhang, Xiaosong
- 《5th International Conference on Cloud and Robotics 》
- 2018年
- NOV 12-14, 2018
- Paris, FRANCE
- 会议
Drying performance of a novel compressed air drying method using different liquid desiccants, including LiCl solution, LiBr solution and mixed solutions (LiCl/CaCl2), is compared by experiments. It is found that drying performance of LiCl solution is better than that of LiBr solution. Besides, drying performance of three mixed solutions (44%, 46% and 49%) selected is similar to that of 40% LiCl solution, verifying the feasibility of substituting single solution with much cheaper mixed solution. The water vapor pressure of mixed solutions and LiCl solution is same in experiments, therefore it can be selected as an indicative factor to evaluate substitute of LiCl solution. Moreover, the cost of the three mixed solutions is 18% cheaper than that of 40% LiCl solution at least, which shows significant economization in application. Finally, system performance of the compressed air drying system is analyzed. The dew point of outlet compressed air could reach -7.7 degrees C at operating pressure of 0.8 MPa, indicating the dryness can satisfy requirement of various industrial applications which used typical electricity-driven cooling-drying method. The solution temperature of regeneration could reach 70 degrees C, validating that it is feasible to use waste heat recycled from the air compressor to drive solution regeneration. (C) 2018 Elsevier Ltd. All rights reserved.
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