纳米材料治理水体复合污染的应用基础研究及工程示范
项目来源
国（略）研（略）(（略）D（略）
项目主持人
刘（略）
项目受资助机构
南（略）
项目编号
2（略）Y（略）2（略）0（略）
立项年度
2（略）
立项时间
未（略）
研究期限
未（略） （略）
项目级别
国（略）
受资助金额
0（略）万（略）
学科
纳（略）
学科代码
未（略）
基金类别
“纳（略） ”重点专项
关键词
纳（略） （略）级（略）;（略）效（略） （略）程（略）水（略）术（略）N（略）t（略）n（略）g（略） （略）-（略）l（略）a（略）a（略）r（略） （略）f（略）m（略） （略）e（略）;（略）m（略）t（略）i（略）p（略）e（略）;（略）t（略）t（略）t（略）t
参与者
张（略）
参与机构
清华大学；南（略） ；山东大学
项目标书摘要：纳（（略）水处理技术革新提供（略）负载于毫米级多孔载（略）结构特征的纳米复合（略）术实用化的主流方法（略）技术领域的研究往往（略）主，对工业废水与区（略）机—无机复合污染的（略）本课题围绕水中有机（略）理，创制出系列新型（略）展了基于“闪速冷冻（略）基于“爆发成核”的（略）实现了锆系、镧系等（略）；揭示了相关材料深（略）、机制与若干限域特（略）材料深度净污过程、（略）了科学依据与方法支（略）以锆系纳米复合材料（略）饮用水深度处理集成（略）1000 m3/d（略） m3/d)等工业（略）(50 m3/d)（略）；并在加拿大、香港（略）复合材料的地表水深（略）/d)应用验证。今（略）合材料深度净污机制（略），进一步升级完善基（略）处理技术炳持续拓展（略）
Applicati（略）: The rap（略）ent of na（略）y provide（略）tunities （略） innovati（略）ced water（略）To advanc（略）cation of（略）logy in p（略）ter treat（略）eparation（略）cale nano（略）aterials （略）ale inner（略）pace has （略）ed as an （略）pproach.H（略）current r（略）environme（略）chnology （略）ses on th（略） solution（略） single p（略）d the kno（略）t the adv（略）ment of t（略）al wastew（略）gional dr（略）r contain（略）-inorgani（略）ollution （略）cking.Foc（略）e deep re（略）ganic-ino（略）lex pollu（略）tudy inve（略）ety of na（略）s for wat（略）t,and dev（略）host pore（略）ng techno（略）on flash （略）d the nan（略）ize-adjus（略）logy base（略）nucleatio（略）zed the t（略）nufacture（略）um-and la（略）ed nanoco（略）e deconta（略）rformance（略） mechanis（略）unusual p（略）nder nano（略） were unc（略）iding the（略） basis an（略）gy suppor（略）ture-acti（略）zation on（略）mposites.（略）,this stu（略）loped the（略） processe（略） on the z（略）sed nanoc（略）r advance（略） on indus（略）water and（略）rinking w（略）ucting th（略）tion proj（略） wastewat（略）ctroplati（略）0 m3/d)an（略）d circuit（略）000 m3/d)（略） regional（略）ater(50 m（略）ing high （略）rsenic an（略）Also,the （略）moval of （略）from surf（略）y the lan（略）d nanocom（略）been veri（略） pilot-sc（略）in Canada（略）ong(30 m3（略）efforts w（略）tained on（略）ying mech（略）dvanced d（略）ion of th（略）sites,on （略）ctivity a（略）f the nan（略）,and on u（略）d spreadi（略）nced wate（略） processe（略）nanocompo（略）
项目受资助省
江（略）
1.纳米材料治理水体复合污染的应用基础研究及工程示范最终报告(Application research and project of nanomaterials for the treatment of water pollution)
- 关键词：
- 水污染、纳米材料、持久性有毒污染物、降解机制、Water pollution、nanomaterials、persistent toxic pollutants、degradation mechanisms
- 刘洋；
- 《清华大学；》
- 2021年
- 报告
人类活动已使天然水体受到不同程度的污染，导致严重的水质性缺水。通过水处理去除污水、废水和饮用水中的重金属、砷、氟和各种有机微污染物等毒害物质，是解决水质性缺水的根本途径。纳米材料(Nanomaterials,NMs)因其极高的比表面积和反应活性，在水中污染物的吸附去除和催化降解等方面具有巨大的潜力，为解决传统的水污染治理技术难题提供了可能的途径。本课题围绕NMs与水中污染物界面作用的构效关系及其调控机制，研发选择性识别水中持久性有毒污染物的纳米探针，发展系列高效吸附/催化降解水中持久性有毒污染物的NMs,开发基于天然黏土矿物NMs原位吸附治理技术的高效吸附/催化降解水中持久性有毒污染物功能化纳米探针。制备得到的Fe-海藻酸水凝胶、电化学还原氧化石墨烯、生物炭及磷酸处理生物炭等纳米材料显示出优异污染物去除性能，达标对饮用水或废水中残留目标污染物。开发了级铁—没食子酸金属有机框架材料、核壳式Fe-Pd/C复合材料、金属有机框架/共价有机框架(MOF/COF)杂化材料、超细Pd纳米颗粒的苯并噻唑连接共价有机框架材料、超细零价铁均匀负载多孔材料、碳包裹Fe3O4纳米材料及核壳式复合Fe-C蒙脱土复合材料、Fe掺杂钠锰矿和氧化铝纳米纤维催化膜等天然黏土矿物NMs,在有机污染物去除及检测方面显示出优异的性能和应用前景，通过该课题在上述方面的深入研究，推动了环境纳米材料和污染治理技术的发展，为解决制约环境纳米技术和环境污染治理的关键科学问题提供了技术支撑和理论支持。Natural water have been polluted by human activities,resulting in severe water shortage.The removal of heavy metals,arsenic,fluorine and various organic micro-pollutants in sewage,waste water and drinking water by water treatment is the fundamental way to solve the water shortage.Nanomaterials(NMs)have great potential in adsorption removal and catalytic degradation of pollutants in water due to their extremely high specific surface area and reactivity,providing a possible approach to solve the traditional technical problems of water pollution.This topic focuses on the structure-activity relationship and regulation mechanism of interface interaction between NMs and water pollutants,develops nanoprobes for selective identification of persistent toxic pollutants in water,and develops a series of NMs for efficient adsorption/catalytic degradation of persistent toxic pollutants in water.The development of functional nanoprobes for efficient adsorption/catalytic degradation of persistent toxic pollutants in water based on natural clay minerals NMs in-situ adsorption treatment technology provides a great opportunity to solve environmental pollution problems.Fe-alginate hydrogel,electrochemical reduction graphene oxide,biochar,phosphoric acid treated biochar and other nanomaterials prepared showed excellent pollutant removal performance,meeting the target residual pollutants in drinking water or wastewater.The development level of iron-gallic acid metal organic framework material,core-shell type Fe-Pd/C composite material,metal organic framework/covalent framework(MOF/COF package)hybrid materials,ultra-fine Pd nanoparticles benzothiazole connection covalent organic framework material,superfine zero-valent iron uniform load porous materials,carbon parcel Fe3O4 nanomaterials and core-shell type compound Fe-Natural clay minerals NMs,such as C montmorillonite composite material,Fe doped Sodium-manganese ore and alumina nanofiber catalytic film,show excellent performance and application prospect in the removal and detection of organic pollutants.Through the in-depth study of the subject in the above aspects,promote the development of environmental nanomaterials and pollution control technology.It provides technical and theoretical support for solving the key scientific problems restricting environmental nanotechnology and environmental pollution control.
...2.水处理过程中纳米材料和污染物的转化与归趋最终报告
- 关键词：
- 纳米材料、环境转化、水处理、表面过程、Nanomaterials、Environmental transformation、Water treatment、Surface process
- 刘景富；
- 《中国科学院生态环境研究中心；》
- 2021年
- 报告
在本年度研究中，课题重点关注了水处理过程中纳米材料及污染物转化过程，包括，水处理过程中污染物的转化，光降解卤代污染物过程毒性中间产物的原位监控,TiO2 对天然有机质的转化，消毒过程溴代消毒副产物的生成。同时，研究还从原子尺度研究了卤代污染物在Pd催化剂表面催化/电催化还原脱卤过程；最后释放评估了树脂基纳米氧化锆复合材料(HZO@D201)在水处理应用中纳米颗粒的释放和转化规律，为设计实用性水处理材料提供了指导。In this year’s research,the subject focused on the conversion of nanomaterials and pollutants in the water treatment process,including the conversion of pollutants in the water treatment process,the in-situ monitoring of toxic intermediates in the process of photodegradation of halogenated pollutants,and the impact of TiO2 on natural The conversion of organic matter,the generation of brominated disinfection by-products in the disinfection process.At the same time,the study also studied the catalytic/electrocatalytic reduction and dehalogenation process of halogenated pollutants on the surface of Pd catalyst from the atomic scale;finally released the evaluation of the resin-based nano-zirconia composite material(HZO@D201)in water treatment applications.The law of release and transformation provides guidance for the design of practical water treatment materials.
...3.基于纳米复合材料的水处理集成技术开发与应用示范—最终报告(Concluding report of nano-enabling water treatment technology)
- 关键词：
- 纳米技术、吨级生产、限域效应、示范工程、水处理技术、Nanotechnology、Ton-scale manufacture、Confinement effect、Demonstration project、Water treatment
- 张孝林；
- 《南京大学；》
- 2021年
- 报告
纳米科技的快速发展为深度水处理技术革新提供了新的机遇。将纳米颗粒负载于毫米级多孔载体材料中制备成具有限域结构特征的纳米复合材料是推进纳米水处理技术实用化的主流方法。然而，目前水处理纳米技术领域的研究往往以单一污染的模拟溶液为主，对工业废水与区域饮用水中普遍存在的有机—无机复合污染的深度处理缺乏深入了解。本课题围绕水中有机—无机复合污染的深度处理，创制出系列新型水处理纳米复合材料，发展了基于“闪速冷冻”的载体孔径调控技术与基于“爆发成核”的纳米颗粒尺寸调控技术，实现了锆系、镧系等纳米复合材料的吨级量产；揭示了相关材料深度净化特征污染物的性能、机制与若干限域特性，为深入理解纳米复合材料深度净污过程、实现材料的构效优化提供了科学依据与方法支撑；在此基础上，开发了以锆系纳米复合材料为核心的工业废水与区域饮用水深度处理集成工艺，实现了电镀园区(1000 m3/d)、集成电路(1000 m3/d)等工业废水与高砷氟区域饮用水(50 m3/d)深度处理的工程应用示范；并在加拿大、香港等地实现了基于镧系纳米复合材料的地表水深度除磷中试(30 m3/d)应用验证。今后研究将继续关注纳米复合材料深度净污机制，提高材料构效调控水平，进一步升级完善基于纳米复合材料的深度水处理技术炳持续拓展其应用空间。The rapid development of nanotechnology provides new opportunities for process innovation in advanced water treatment.To advance the application of nanotechnology in practical water treatment,the preparation of macro-scale nanocomposite materials with nanoscale inner confined space has been reckoned as an effective approach.However,the current research in environmental nanotechnology mainly focuses on the simulated solution containing single pollutant,and the knowledge about the advanced treatment of the industrial wastewater and regional drinking water containing organic-inorganic complex pollution is still lacking.Focusing on the deep removal of organic-inorganic complex pollution,this study invented a variety of nanocomposites for water treatment,and developed the host pore-manipulating technology based on flash freezing and the nanoparticle size-adjusting technology based on burst nucleation,and realized the ton-scale manufacture of zirconium-and lanthanum-based nanocomposites.The decontamination performance,underlying mechanism and some unusual phenomenon under nanoconfinement were uncovered,providing the scientific basis and methodology support for structure-activity optimization on the nanocomposites.Furthermore,this study has developed the integrated processes centering on the zirconium-based nanocomposite for advanced treatment on industrial wastewater and regional drinking water,constructing the demonstration projects on the wastewater from electroplating park(1000 m3/d)and integrated circuit industry(1000 m3/d),and on the regional drinking water(50 m3/d)containing high levels of arsenic and fluorine.Also,the advanced removal of phosphorus from surface water by the lanthanum-based nanocomposite has been verified by the pilot-scale assays in Canada and Hong Kong(30 m3/d).Future efforts will be maintained on the underlying mechanism for advanced decontamination of the nanocomposites,on structure-activity adjustment of the nanocomposites,and on upgrading and spreading the advanced water treatment processes based on nanocomposites.
...4.纳米材料治理水体复合污染的应用基础研究及工程示范年度报告(Treatment of Water Contaminated by organic/inorganic pollutants with Nanomaterials:Basical study and field application)
- 关键词：
- 纳米材料、水处理、表面过程、环境转化、生态风险评估、工程应用、Nanomaterials、Water treatment、Surface process、Environmental transformation、Eco risk assessment、Field appication
- 刘景富；
- 《中国科学院生态环境研究中心；》
- 2019年
- 报告
本项目聚焦于将纳米材料用于水处理涉及到的纳米材料设计、去污过程研究、生态风险评价到示范工程应用等四个方面，在本年度，项目组取得如下成果: 1)制备了系列(光电)催化剂，设计了自偏压光电催化(PFC)体系，实现水中的有机污染物高效、持续降解和Cr(VI)和As(III)等重金属离子的去除；构筑了银团簇、g-C3N4偶联聚多巴胺包裹的Galinstan液态金属壳核纳米杂交体(g-C3N4@Galinstan-PDA)纳米探针、Ti3C2 MXenes复合功能纳米探针，构建复合纳米探针并发展了高灵敏的光电化学传感器; (2)原位研究了污染物在环境条件下的转化，明确了纳米材料的晶面/粒径影响催化活性的实质；阐明了金属配合物形态转化过程研究方法，提出了在水处理过程中具有重要应用潜能的低成本金属化合物催化剂的设计新策略；建立了利用双同位素技术追踪金属纳米材料环境转化过程的方法，初步阐明了纳米Ag在环境条件下的转化过程; (3)建立了水污染治理用纳米材料健康效应评价体系，评价了污染物在孕期小鼠中的生物效应及分子机制；探究水污染治理用纳米材料—生物相互作用的机制，并初步建立纳米生物效应预测模型；采用发光菌、细胞、斑马鱼等系统评估和对比了纳米复合材料深度处理工艺前后的生物毒性削减规律。 (4)揭示了限域空间内纳米颗粒与污染物相互作用的若干特性；完善了树脂基复合纳米材料HZO@201的规模化制备工艺, This project focuses on the nanomaterial design,decontamination process,ecological risk assessment,and field application involved in the use of nanomaterials in water treatment.In this year,the project team achieved the following results: 1)A series of(photo-/electric-)catalysts were prepared and a self-biased photocatalytic(PFC)system was designed to achieve efficient and continuous degradation of organic pollutants in water and the removal of heavy metal ions such as Cr(VI)and As(III);Silver clusters,g-C3N4 coupled polydopamine-coated Galinstan liquid metal shell-core nano-hybrid(g-C3N4@Galinstan-PDA)nano-probes,Ti3C2 MXenes composite functional nano-probes,constructing composite nano-probes and developing high Sensitive photoelectrochemical sensor; (2)In situ research on the conversion of pollutants under environmental conditions,clarifies the essence of the crystal surface/particle size of nanomaterials affecting catalytic activity;clarifies the research method of the transformation process of metal complexes,and proposes in the water treatment process A new strategy for the design of low-cost metal compound catalysts with important application potentials.A method for tracking the environmental conversion process of metal nanomaterials using dual isotope technology was established,and the conversion process of nano Ag under environmental conditions was initially clarified; (3)Established a health effect evaluation system for nanomaterials for water pollution control,evaluated biological effects and molecular mechanisms of pollutants in mice during pregnancy;explored the mechanism of nanomaterial-biological interactions for water pollution control,and initially established nanometers Biological effect prediction model;the phototoxic bacteria,cells,zebrafish,and other systems were used to evaluate and compare the biotoxicity reduction laws before and after the nanocomposite advanced treatment process. (4)Revealed several characteristics of the interaction between nanoparticles and pollutants in confined space;improved the large-scale preparation process of resin-based composite nanomaterials HZO@201,and carried out the construction of ton-scale production lines and ton-scale production of related composite nanomaterials The preliminary investigation work of the demonstration project for the in-depth treatment of regional drinking water and typical industrial wastewater was carried out.
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